Электронная книга: Gudmundsdottir Anna D. «Nitrenes and Nitrenium Ions»

Nitrenes and Nitrenium Ions

Featuring contributions respected leaders in the field, Nitrene and Nitrenium Ions is the first comprehensive book to explore the role of reactive intermediate nitrene and nitrenium ions in chemistry and biochemistry. Covering a broad range of topics, including ultrafast studies, computational studies, behavior in aqueous solution, electronic structures, and reactions with aromatic compounds, this valuable resource will empower graduate students and researchers to better understand and expand their synthetic utility.

Издательство: "John Wiley&Sons Limited"

ISBN: 9781118560938

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  • Nitrenium ion — A nitrenium ion (also called: aminylium ion) in organic chemistry is a reactive intermediate based on nitrogen with both an electron lone pair and a positive charge and with two substituents (R2N+).[1] Nitrenium ions are isoelectronic to carbenes …   Wikipedia

  • Reaction intermediate — A reaction intermediate or an intermediate is a molecular entity that is formed from the reactants (or preceding intermediates) and reacts further to give the directly observed products of a chemical reaction. Most chemical reactions are stepwise …   Wikipedia

  • Diradical — Not to be confused with biradical. A diradical in organic chemistry is a molecular species with two electrons occupying two degenerate molecular orbitals (MO).[1][2] They are known by their higher reactivities and shorter lifetimes. In a broader… …   Wikipedia