Электронная книга: Roderick Bates «Organic Synthesis Using Transition Metals»

Organic Synthesis Using Transition Metals

Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed– established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from «classical» organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.

Издательство: "John Wiley&Sons Limited"

ISBN: 9781119942856

электронная книга

Купить за 13268.06 руб и скачать на Litres

Другие книги схожей тематики:

АвторКнигаОписаниеГодЦенаТип книги
Ken TanakaRhodium Catalysis in Organic Synthesis. Methods and ReactionsAn essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their… — @John Wiley&Sons Limited, @ @ @ @ Подробнее...
21541.08электронная книга
Ramon Torres RiosThe Pauson-Khand Reaction. Scope, Variations and ApplicationsThe Pauson-Khand reaction is an important reaction in the field of organic chemistry. It involves the transition-metal catalysed cycloaddition of an alkyne, an alkene and carbon monoxide, to produce… — @John Wiley&Sons Limited, @ @ @ @ Подробнее...
2181.42электронная книга
Ramon Torres RiosThe Pauson-Khand Reaction. Scope, Variations and ApplicationsThe Pauson-Khand reaction is an important reaction in the field of organic chemistry. It involves the transition-metal catalysed cycloaddition of an alkyne, an alkene and carbon monoxide, to produce… — @John Wiley&Sons Limited, @ @ @ @ Подробнее...
13126.82электронная книга

Look at other dictionaries:

  • Organic light-emitting diode — Demonstration of a flexible OLED device A green emitting OLED device An …   Wikipedia

  • Metal-organic framework — Metal Organic Frameworks are crystalline compounds consisting of metal ions or clusters coordinated to often rigid organic molecules to form one , two , or three dimensional structures that can be porous. In some cases, the pores are stable to… …   Wikipedia

  • Coupling reaction — A coupling reaction in organic chemistry is a catch all term for a variety of reactions where two hydrocarbon fragments are coupled with the aid of a metal catalyst. In one important reaction type a main group organometallic compound of the type… …   Wikipedia

  • Reacción de acoplamiento — Una reacción de acoplamiento en química orgánica es un término que se aplica a todas aquellas reacciones orgánicas en el que dos fragmentos de hidrocarburos se unen o se enlazan para formar una sola molécula, con la ayuda de un catalizador… …   Wikipedia Español

  • Aldol reaction — The aldol reaction is a powerful means of forming carbon–carbon bonds in organic chemistry.[1][2][3] Discovered independently by …   Wikipedia

  • Center of Excellence in Nanotechnology at AIT — Center of Excellence at AIT CoEN @ AIT Motto There is no sky to limit us at the bottom Type Center of Excellence Endowment …   Wikipedia

  • Mathematics and Physical Sciences — ▪ 2003 Introduction Mathematics       Mathematics in 2002 was marked by two discoveries in number theory. The first may have practical implications; the second satisfied a 150 year old curiosity.       Computer scientist Manindra Agrawal of the… …   Universalium

  • organometallic compound — ▪ chemical compound Introduction  any member of a class of substances containing at least one metal to carbon bond in which the carbon is part of an organic group. Organometallic compounds constitute a very large group of substances that have… …   Universalium

  • chemical compound — Introduction  any substance composed of identical molecules consisting of atoms (atom) of two or more chemical elements (chemical element).       All the matter in the universe is composed of the atoms of more than 100 different chemical elements …   Universalium

  • Cluster chemistry — In chemistry, a cluster is an ensemble of bound atoms intermediate in size between a molecule and a bulk solid. Clusters exist of diverse stoichiometries and nuclearities. For example, carbon and boron atoms form fullerene and borane clusters,… …   Wikipedia

  • Desulfonylation reactions — are chemical reactions leading to the removal of a sulfonyl group from organic compounds. As the sulfonyl functional group is electron withdrawing, methods for cleaving the sulfur carbon bonds of sulfones are typically reductive in nature.… …   Wikipedia


We are using cookies for the best presentation of our site. Continuing to use this site, you agree with this.