Книга: Elizabeth Ntantie and Jeffery Wardeska «Equilibrium and Charge Transfer:»
Производитель: "LAP Lambert Academic Publishing" Cyano-bridged mixed valence compounds have been known to exist since 1704, but a lot of interest in the bi-nuclear and tri-nuclear species has emerged only more recently. The growing interest in these complexes is due mainly to their promising and useful applications in electrochromism, molecular magnetism and molecular electronics. These properties are activated by the excitation of their metal-to-metal charge transfer (MMCT) transition. This book characterizes aqueous solutions of the FeHEDTA / Fe(CN)6 4- system which form intensely colored solutions that absorb strongly in the visible/NIR region of the electromagnetic spectrum. Typically binuclear (Fe(III)-Fe(II)) and trinuclear (Fe(III)-Fe(II)-Fe(III)) complexes are formed. Information on reorganizational parameters, electronic coupling between metal centers, molar absorptivities, equilibrium constants, and delocalization factors are discussed for binuclear and trinuclear Fe(III)/Fe(II) complexes, and compared to similar systems... ISBN:9783846500361 Издательство: "LAP Lambert Academic Publishing" (2011)
ISBN: 9783846500361 |
См. также в других словарях:
Charge-transfer complex — A charge transfer complex (CT complex) or electron donor acceptor complex is an association of two or more molecules, or of different parts of one very large molecule, in which a fraction of electronic charge is transferred between the molecular… … Wikipedia
Business and Industry Review — ▪ 1999 Introduction Overview Annual Average Rates of Growth of Manufacturing Output, 1980 97, Table Pattern of Output, 1994 97, Table Index Numbers of Production, Employment, and Productivity in Manufacturing Industries, Table (For Annual… … Universalium
Homogeneous charge compression ignition — Thermodynamics … Wikipedia
ionosphere and magnetosphere — ▪ atmospheric science Introduction regions of Earth s (Earth) atmosphere in which the number of electrically charged particles ions (ion) and electrons (electron) are large enough to affect the propagation of radio waves (electromagnetic… … Universalium
international payment and exchange — ▪ economics Introduction international exchange also called foreign exchange respectively, any payment made by one country to another and the market in which national currencies are bought and sold by those who require them for such… … Universalium
Thermal management of electronic devices and systems — Heat generated by electronic devices and circuitry must be dissipated to improve reliability and prevent premature failure. Techniques for heat dissipation can include heatsinks and fans for air cooling, and other forms of computer cooling such… … Wikipedia